Synthesis of a new type of binucleating macrocycle incorporating both the dithiolato and diimino functionality and a polyether compartment
Abstract
A series of novel macrocyclic systems have been prepared using 5-chloro-4-formyl pyrazoles (via selective N-1 alkylation) as heterocyclic building blocks; a binuclear NiII–TlI complex derived from such a ligand has also been characterised.
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