Issue 18, 1989

Characterisation of three isomers of trans-[IrCl2(EMe2Ph)4]ClO4(E = P or As) each containing adjacent parallel phenyl rings

Abstract

The major of three isomers of trans-[IrCI2(EMe2Ph)4]CIO4(E = P or As), identified by their low temperature 31P{1H}, 13C{1H}, and 1H n.m.r. spectra, corresponds to that found in the crystal (E = P) and each contains adjacent and parallel phenyl rings leading to 1H n.m.r. (phenyl) resonances as high-field as δ 5.7.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1989, 1351-1353

Characterisation of three isomers of trans-[IrCl2(EMe2Ph)4]ClO4(E = P or As) each containing adjacent parallel phenyl rings

A. J. Deeming, S. Doherty, J. E. Marshall and N. I. Powell, J. Chem. Soc., Chem. Commun., 1989, 1351 DOI: 10.1039/C39890001351

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