The decarboxylation reaction catalysed by threo-Ds-3-isopropylmalate dehydrogenase from the thermophile Thermus thermophilus HB-8 has been firmly established to proceed with retention of configuration at the C-3 position of (2R,3S)-isopropymalic acid.
K. Kakinuma, K. Ozawa, Y. Fujimoto, N. Akutsu and T. Oshima, J. Chem. Soc., Chem. Commun., 1989, 1190 DOI: 10.1039/C39890001190
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