Issue 17, 1989
From the journal:

Journal of the Chemical Society, Chemical Communications

Synthesis and structural characterisation of [Au8Cl2(PPh3)6Rh(CNC 8H9)2](PF6): a novel hetero-metallic cluster compound of gold with a hemi-spherical topology

Simon G. Bott,   D. Michael P. Mingos  and  Michael J. Watson  

Abstract

[Au8Cl2(PPh3)6 Rh(CNC8H9)2](PF6) has been synthesised by the NaBH4 reduction of a mixture of Au(PPh3)Cl and Rh(CNC8H9)3Cl, and a single crystal X-ray study has shown that it has a hemispherical geometry of gold atoms based on an icosahedron, with the rhodium atom occupying the centre of the open face and bonded to all eight gold atoms.

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Article information

DOI
https://doi.org/10.1039/C39890001192
Article type
Paper

J. Chem. Soc., Chem. Commun., 1989, 1192-1193

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Synthesis and structural characterisation of [Au8Cl2(PPh3)6Rh(CNC 8H9)2](PF6): a novel hetero-metallic cluster compound of gold with a hemi-spherical topology

S. G. Bott, D. M. P. Mingos and M. J. Watson, J. Chem. Soc., Chem. Commun., 1989, 1192 DOI: 10.1039/C39890001192

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