The crystal structure of [Bu4N][lr2(mdcbi)(CO)4]·CH2Cl2(H3mdcbi = 2-methylimidazole-4,5-dicarboxylic acid) shows a new type of stacking in which the two iridium atoms of the binuclear complex are both involved in extended metal–metal chains at nearly identical distances.
G. Net, C. Bayón, W. M. Butler and P. Rasmussen, J. Chem. Soc., Chem. Commun., 1989, 1022 DOI: 10.1039/C39890001022
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