Catalytic hydrosilylation of acetyl complexes, M–COMe affords α-siloxyethyl complexes, M–CH(OSiR3)Me, in quantitative yields; the hydrosilylation of an acetylmanganese complex, Mn(CO)5–COMe, produces C2–C4 alkenes by a repeating reduction–carbonylation sequence, which serves as a model reaction for the chain propagation step of the Pichler–Schulz mechanism.
M. Akita, O. Mitani and Y. Moro-oka, J. Chem. Soc., Chem. Commun., 1989, 527 DOI: 10.1039/C39890000527
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