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Issue 17, 1989
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Cobalt catalysed ring-opening carbonylation of cyclic ethers using N-(trimethylsilyl)amines

Abstract

N-(Trimethylsilyl)amines direct ring-opening carbonylation of a variety of cyclic ethers such as oxiranes (13), oxetane (4), tetrahydrofuran (5), and 1,3-dioxolane (6) in the presence of a catalytic amount of Co2(CO)8 under carbon monoxide pressure to give siloxy amides.

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Article type: Paper
DOI: 10.1039/C39890001253
J. Chem. Soc., Chem. Commun., 1989, 1253-1254

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    Cobalt catalysed ring-opening carbonylation of cyclic ethers using N-(trimethylsilyl)amines

    Y. Tsuji, M. Kobayashi, F. Okuda and Y. Watanabe, J. Chem. Soc., Chem. Commun., 1989, 1253
    DOI: 10.1039/C39890001253

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