By using two different substrates under various experimental conditions, the value KD/KH= 2.55 ± 0.28 has been found for the solvent isotope effect on the equilibrium of formation of the nitrosonium/nitrous acidium ion over the pH range 1–5.
A. Castro, M. Mosquera, M. F. R. Prieto, J. A. Santaballa and J. V. Tato, J. Chem. Soc., Perkin Trans. 2, 1988, 1963 DOI: 10.1039/P29880001963
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