The reactions between [ReH5(PPh3)3] and [Au(PR3)]PF6(R = Et or Ph) in acetone–CH2Cl2 give the complexes [ReH5(PPh3)3{Au(PR3)}]PF6. Treatment of [ReH5(PPh3)3{Au(PPh3)}]PF6 with NEt3 affords the ReAu2 cluster [ReH4(PPh3)3{Au(PPh3)}2]PF6. The complexes have been characterized by 1H n.m.r., 31P-{1H} n.m.r., and i.r. spectroscopies as well as by cyclic voltammetry.
G. A. Moehring and R. A. Walton, J. Chem. Soc., Dalton Trans., 1988, 1701 DOI: 10.1039/DT9880001701
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