2-[3-(o)-Chlorophenylsulphonylureido]-4-methoxy-6-methyl-1,3,5-triazine (3) adopts a coplanar cis-amide conformation in non-aqueous solvents, in contrast to the trans-conformation normally preferred by simple arylamides; the planar conformation in (3) arises as a result of intramolecular NH ![[dash dash, graph caption]](https://www.rsc.org/images/entities/char_e091.gif)
N hydrogen bonding.
P. Camilleri, B. Odell, H. S. Rzepa and R. N. Sheppard, J. Chem. Soc., Chem. Commun., 1988, 1132 DOI: 10.1039/C39880001132
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