Issue 16, 1988
From the journal:

Journal of the Chemical Society, Chemical Communications

Rhenium complexes containing an η2-thiocarbamoyl group: synthesis, electrochemistry, and crystal structure of [Re(S2CNEt2)2(SCNEt2)(PPh3)]ClO4

Akio Ichimura,   Yoshiaki Yamamoto,   Takayoshi Kajino,   Toyokichi Kitagawa,   Hiroo Kuma  and  Yoshihiko Kushi  

Abstract

A new redox couple of rhenium complexes, [ReIII(S2CNEt2)2(SCNEt2)(PPh3)] and [ReIV(S2CNEt2)2(SCNEt2)(PPh3)]ClO4, has been isolated and electrochemically characterized; the η2-co-ordination of the N,N-diethylthiocarbamoyl group in the latter has been confirmed by X-ray analysis.

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Article information

DOI
https://doi.org/10.1039/C39880001130
Article type
Paper

J. Chem. Soc., Chem. Commun., 1988, 1130-1131

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Rhenium complexes containing an η2-thiocarbamoyl group: synthesis, electrochemistry, and crystal structure of [Re(S2CNEt2)2(SCNEt2)(PPh3)]ClO4

A. Ichimura, Y. Yamamoto, T. Kajino, T. Kitagawa, H. Kuma and Y. Kushi, J. Chem. Soc., Chem. Commun., 1988, 1130 DOI: 10.1039/C39880001130

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