Experimental ΔG‡(enantiomerization) values for trans-1,2-disubstituted cyclopropanes correlate in strict linearity with the sum of substituent radical stabilization energy terms; the two ends of the 1,3-disubstituted trimethylene diradicals implicated in these thermal enantiomerization reactions appear to be thermochemically independent.
J. E. Baldwin, J. Chem. Soc., Chem. Commun., 1988, 31 DOI: 10.1039/C39880000031
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