Issue 15, 1988

Reactions of a glycidyl radical equivalent with 2-functionalised allyl stannanes

Abstract

Reaction of 2-bromo-N-benzoylglycine methyl ester with 2-functionalised allyl stannane reagents under radical conditions provides a new route to α-alkylated amino acids in good yield, as exemplified by the facile synthesis of 4-methylene glutamate.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1988, 1030-1031

Reactions of a glycidyl radical equivalent with 2-functionalised allyl stannanes

J. E. Baldwin, R. M. Adlington, C. Lowe, I. A. O'Neil, G. L. Sanders, C. J. Schofield and J. B. Sweeney, J. Chem. Soc., Chem. Commun., 1988, 1030 DOI: 10.1039/C39880001030

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