Issue 15, 1988

A new route to functionalised hydroazulenes. Synthesis of (±)-confertin

Abstract

The advanced confertin intermediate (13) has been synthesised in 20% yield from a simple dihydrocinnamic acid precursor, the hydroazulene skeleton having been constructed by rhodium(II) mandelate-catalysed cyclisation–ring expansion of an α-diazoketone.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1988, 1028-1030

A new route to functionalised hydroazulenes. Synthesis of (±)-confertin

M. Kennedy and M. A. McKervey, J. Chem. Soc., Chem. Commun., 1988, 1028 DOI: 10.1039/C39880001028

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