Issue 16, 1987
From the journal:

Journal of the Chemical Society, Chemical Communications

The first example of a niobium–sulphide–thiolate cluster: metal–metal bonding and µ4-sulphide groups in tetranuclear [Nb4S2(SPH)12]4–

Jeffrey L. Seela,   John C. Huffman  and  George Christou  

Abstract

Reaction of Nb2Cl6(Me2S)3 with of excess of LiSPh·THF (THF = tetrahydrofuran) leads to formation of Li4[Nb4S2(SPh)12]·4THF: the crystal structure shows the tetra-anion to contain a metal–metal bonded Nb4 square with a µ4-S2– atom both above and below the metal plane.

About
Cited by
Related
Download options Please wait...

Article information

DOI
https://doi.org/10.1039/C39870001258
Article type
Paper

J. Chem. Soc., Chem. Commun., 1987, 1258-1260

Permissions

Request permissions

The first example of a niobium–sulphide–thiolate cluster: metal–metal bonding and µ4-sulphide groups in tetranuclear [Nb4S2(SPH)12]4–

J. L. Seela, J. C. Huffman and G. Christou, J. Chem. Soc., Chem. Commun., 1987, 1258 DOI: 10.1039/C39870001258

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Spotlight

Advertisements