The reaction of SC(NHPh)2 with [Au(CH2)2PPh2]2Cl2 followed by addition of base has led to the isolation and X-ray crystal structure analysis of a gold(II) ylide dimer, [Au(CH2)2PPH2]2[SSC(NPh)(NHPh)]2 which is the first example of a thiourea containing catenated disulphide co-ordinated to a metal centre.
D. D. Heinrich and J. P. Fackler, J. Chem. Soc., Chem. Commun., 1987, 1260 DOI: 10.1039/C39870001260
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