Free radicals produced successively at C-5 and C-1 from corresponding D-xylopyranose-based bromides add to acrylonitrile and methyl acrylate to give products with β-propionitrile or β-propionate substituents at these positions; some steric control can be achieved in the reactions, and the 4,8-anhydroundecanose derivative (13) is produced with good selectivity.
R. Blattner, R. J. Ferrier and R. Renner, J. Chem. Soc., Chem. Commun., 1987, 1007 DOI: 10.1039/C39870001007
To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.
If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.
If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.
Read more about how to correctly acknowledge RSC content.
Please wait while we load your content...