Reaction of optically active π-allylpalladium complexes with Cl3SiSiMe3 or Cl2PhSiSiMe3 in the presence of triphenylphosphine was found to proceed with retention of configuration to give optically active allylsilanes in high yields.
T. Hayashi, A. Yamamoto, T. Iwata and Y. Ito, J. Chem. Soc., Chem. Commun., 1987, 398 DOI: 10.1039/C39870000398
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