1,1,1-Trichloro-2,2,2-trimethyldisilane: reagent for stereospecific silylation of π-allylpalladium complexes
Abstract
Reaction of optically active π-allylpalladium complexes with Cl3SiSiMe3 or Cl2PhSiSiMe3 in the presence of triphenylphosphine was found to proceed with retention of configuration to give optically active allylsilanes in high yields.