On the chemisorption of [Ru3(CO)12] and [Os3(CO)12] on silica and alumina
Abstract
I.r. [δ(MH)], Raman [v(M–M)], and Ru K-edge E.X.A.F.S. data on the first chemisorption product of M3(CO)12/SiO2(M = Ru, Os) and Os3(CO)12/Al2O3, indicate a structure of type (µ-H)M3(CO)10(µ-O–O).