The first direct X-ray crystal structure determination of a cytotoxic cyclic peptide from ascidian, ascidiacyclamide, has shown a molecular conformation responsible for its biological activity.
T. Ishida, M. Inoue, Y. Hamada, S. Kato and T. Shioiri, J. Chem. Soc., Chem. Commun., 1987, 370 DOI: 10.1039/C39870000370
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