A series of sterically hindered manganese porphyrins are shown to be shape-selective catalysts for the epoxidation of a variety of dienes; product ration differences for conjugated vs. non-conjugated dienes indicate the existence of at least two competing epoxidation pathways.
K. S. Suslick and B. R. Cook, J. Chem. Soc., Chem. Commun., 1987, 200 DOI: 10.1039/C39870000200
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