Issue 3, 1987

Mild carbon–carbon bond cleavage of carbonyl compounds using pentafluoroiodobenzene bis(trifluoroacetate)

Abstract

Acetophenones, α-hydroxyacetophenones, deoxybenzoin, benzoin, and benzil are cleaved oxidatively with pentafluoroiodobenzene bis-(trifluoroacetate) in wet benzene at room temperature to give the corresponding benzoic acids; cyclohexanone and dimedone are cleaved to give the diacids adipic acid and 3,3-dimethylglutaric acid, respectively.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1987, 202-203

Mild carbon–carbon bond cleavage of carbonyl compounds using pentafluoroiodobenzene bis(trifluoroacetate)

R. M. Moriarty, I. Prakash and R. Penmasta, J. Chem. Soc., Chem. Commun., 1987, 202 DOI: 10.1039/C39870000202

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