Dienone–phenol rearrangement occurs in the reaction of an oxathiolane and dithiolane of 3-oxo-steroids with copper(II) bromide to give 4-methyl-19-norcholesta-1,3,5,(10)-trieno[1,2-b]-dihydroxathiine and -dihydrodithiine, respectively.
J. Y. Satoh, A. M. Haruta, T. Satoh, K. Satoh and T. T. Takahashi, J. Chem. Soc., Chem. Commun., 1986, 1765 DOI: 10.1039/C39860001765
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