Reaction of MoO2Cl2(dmf)2(dmf = dimethylformamide) with 1,4-dihydrazinophthalazine (dhphH6) gives [Et3NH]2[Mo4O11dhphH2], which is shown by an X-ray crystal structure analysis to be a binuclear, oxo-bridged, formally MoIV, diazene complex with bridging molybdate groups; upon acidification the complex reversibly converts into a MoVI derivative of the fully protonated, parent hydrazine.
D. Attanasio, V. Fares and P. Lmperatori, J. Chem. Soc., Chem. Commun., 1986, 1476 DOI: 10.1039/C39860001476
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