A competing 1,3-rearrangement of allyl stannanes has been demonstrated to occur under the normal thermal homolytic allyl transfer reaction conditions which limits the substitution patterns in these processes; two methacrylyl stannanes are described which allow the transfer of the methacrylyl moiety to alkyl bromides and iodides under mild conditions.
J. E. Baldwin, R. M. Adlington, D. J. Birch, J. A. Crawford and J. B. Sweeney, J. Chem. Soc., Chem. Commun., 1986, 1339 DOI: 10.1039/C39860001339
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