Pd0–PPh3 complexes obtained by reduction of X2Pd(PPh3)2, where X is Cl, Br, or I, with various reducing agents, e.g., RLi and Bui2AlH, are neither free Pd(PPh3)2 nor its polymer, those derived from RLi being consistent only with LiXPd(PPh3)2, Li2X2Pd(PPh3)2, and aggregates thereof.
E. Negishi, T. Takahashi and K. Akiyoshi, J. Chem. Soc., Chem. Commun., 1986, 1338 DOI: 10.1039/C39860001338
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