[(cp)2Ti(Te2C6H4)](1)(cp =η5-C5H5) was obtained from (i)[(cp)2 TiCl2] and o-(LiTe)2C6H4, or (ii)[(cp)2TiPh2] and Te, and was shown by temperature-dependent 1H n.m.r. spectroscopy to exist in toluene solution in an envelope conformation, the five-membered TiTe2C2 chelate ring undergoing rapid inversion at room temperature.
H. Köpf and T. Klapötke, J. Chem. Soc., Chem. Commun., 1986, 1192 DOI: 10.1039/C39860001192
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