Regioselective hydroxylation at the C-7 and the C-9 position of ent-kaur-16-ene (2) was achieved via radical cyclization of a hydroxymethyl group introduced at the C-15 position followed by removal of the carbon atom at C-15.
M. Node, T. Kajimoto, N. Ito, J. Tamada, E. Fujita and K. Fuji, J. Chem. Soc., Chem. Commun., 1986, 1164 DOI: 10.1039/C39860001164
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