SCHEDULED MAINTENANCE
The X-ray crystal structure of Ti(BH4)3(PMe3)2 shows that two of the BH4– groups possess unusual geometries involving interaction of the titanium centre with one B–H bond in a ‘side-on’ manner; this geometry resembles one proposed transition state for the approach of a molecule of methane to a transition metal leading to C–H bond cleavage.
J. A. Jensen and G. S. Girolami, J. Chem. Soc., Chem. Commun., 1986, 1160 DOI: 10.1039/C39860001160
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