Issue 12, 1986

A model for the polymerisation of diazomethane by transition metal complexes

Abstract

The reaction of (cod)PtCl(CH3)(cod = cyclo-octa-1,4-diene) with diazomethane to give (cod)Pt(CH3)(CH2Cl), and the facile rearrangement of the latter to (cod)PtCl(CH2CH3), may represent a model for the key steps in the title process.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1986, 943-944

A model for the polymerisation of diazomethane by transition metal complexes

R. McCrindle, G. J. Arsenault, R. Farwaha, M. J. Hampden-Smith and A. J. McAlees, J. Chem. Soc., Chem. Commun., 1986, 943 DOI: 10.1039/C39860000943

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