Photolytic conversion of 1-aryl-1,2,3-triazoles (5) and (14) into the ‘rearranged’ indoles (4) and (15), respectively, provides the first evidence for antiaromatic 1H-azirines, e.g.(8), as reactive intermediates in a photochemical reaction.
G. Mitchell and C. W. Rees, J. Chem. Soc., Chem. Commun., 1986, 399 DOI: 10.1039/C39860000399
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