The cyclic P6(2) is predicted to lie 6 kcal mol–1 above the free 3P2 fragments and to decompos to the latter with an energy barrier of 13 kcal mol–1 using ab initio calculations with different basis sets and correlation methods; it is tempting to suggest that (2) might be detected in an inert matrix at low temperatures (1 cal = 4.184 J.)
M. T. Nguyen and A. F. Hegarty, J. Chem. Soc., Chem. Commun., 1986, 383 DOI: 10.1039/C39860000383
To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.
If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.
If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.
Read more about how to correctly acknowledge RSC content.
Please wait while we load your content...