Vinyl potassium was formed directly from ethene by use of a new butyl-lithium–potassium t-butoxide–tetramethylethylenediamine metallating reagent; typical products were obtained with 1-bromo-octane and, after addition of LiBr in tetrahydrofuran, with benzaldehyde and diphenyl disulphide.
L. Brandsma, H. D. Verkruijsse, C. Schade and P. von Ragué Schleyer, J. Chem. Soc., Chem. Commun., 1986, 260 DOI: 10.1039/C39860000260
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