The preparation and crystal structure of a complex of composition [(NH3)4Pt2(C5H5N2O2)3](SiF6)(NO3)·7H2O is reported which contains two cis-diammineplatinum(III) units bridged by two 1-methyluracilato ligands via N(3) and O(4)(head–head) and in addition has a third 1-methyluracil ligand co-ordinated to one of the two Pt atoms through the deprotonated C(5) position.
H. Schöllhorn, U. Thewalt and B. Lippert, J. Chem. Soc., Chem. Commun., 1986, 258 DOI: 10.1039/C39860000258
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