Observed (from magic angle spinning and static spectra) and calculated 29Si n.m.r. chemical shift tensor data of polycrystalline 4Ca2SiO4·MgCl2 indicate the presence of a new magnesium-containing silicate anion corresponding to the formula Ca8[Mg(SiO4)4|Cl2].
A. Grimmer and F. von Lampe, J. Chem. Soc., Chem. Commun., 1986, 219 DOI: 10.1039/C39860000219
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