Biosynthesis of monensin. The intramolecular rearrangement of isobutyryl-CoA to n-butyryl-CoA
Abstract
The incorporation of [1,3,3′-13C3]isobutyrate into monensin-A in cultures of Streptomyces cinnamonensis reveals an intramolecular rearrangement linking isobutyryl-CoA and n-butyryl-CoA.