SCHEDULED MAINTENANCE
8-Methylene-2-noradamantylidene inserts readily into the γ C–H bond giving 6-methylene-2,4-didehydro-noradamantane rather than the olefin-cycloaddition product, while its higher homolouge 4-methylene-2-adamantylidene reacts exclusively by intramolecular cycloaddition to the olefinic bond yielding 2,4-methano-2,4-didehydroadamantane, a [3.1.1.]propellane.
Z. Majerski, Z. Hameršak and K. Mlinarić-Majerski, J. Chem. Soc., Chem. Commun., 1985, 1830 DOI: 10.1039/C39850001830
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