Incorporation of [1-13c, 18O2]acetate and 18O2 gass into citreoiridin by cultures of Penicillium pulvillorumestablished the origin of the oxygen atoms and provided stereochemical and mechanistic information on the biosynthetic pathway.
P. S. Steyn and R. Vleggaar, J. Chem. Soc., Chem. Commun., 1985, 1531 DOI: 10.1039/C39850001531
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