Rhodium phosphine complexes synthesized in situ on zeolite NaY are active for propene hydroformylation at 150 °C and 1 atm; the catalysts are not stable yet show an enhancement in linear vs. branched products with an increased production of alcohols compared to rhodium zeolites without phosphines.
E. Rode, M. E. Davis and B. E. Hanson, J. Chem. Soc., Chem. Commun., 1985, 1477 DOI: 10.1039/C39850001477
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