Complete synthesis of the series of triangular oxo/sulphido bridged molybdenum(IV) complexes as aqua ions
Abstract
Electrochemical reduction of pairs of MoV2 complexes from [Mo2O4(cys)2]2–, [Mo2O3S(cys)2]2–, and [Mo2O2S2(cys)2]2–(cys = cysteinato) in equimolar amounts, has enabled triangular oxo/sulphido MoIV3 complexes (eight in all) to be synthesised.