The barrier to rotation about the selenium-selenium bond in phenyl benzyl diselenide PhSeSeCH2Ph is determined to be 6.3 kcal mol–1†; as indicated by changes in the proton n.m.r. spectrum at low temperatures; theis is ca. 1.4 kcal mol–1 lower than the barrier in phenyl benzyl disulphide PhSSCH2Ph.
J. E. Anderson and L. Henriksen, J. Chem. Soc., Chem. Commun., 1985, 1397 DOI: 10.1039/C39850001397
To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.
If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.
If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.
Read more about how to correctly acknowledge RSC content.
Please wait while we load your content...