Specific release of translational energy for methyl radical expulsion from certain t-butylamine ions demonstrates the existence of reverse energy barriers to α-cleavage in these amine molecular ions; literature heats of formation of immonium ions may in consequence have a systematic error.
S. Hammerum and P. J. Derrick, J. Chem. Soc., Chem. Commun., 1985, 996 DOI: 10.1039/C39850000996
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