SiO2-bound molybdenum(VI) dimers (Mo–Mo 0.330 nm)with bridging oxygen atoms (Mo-O 0.194 nm), prepared from Mo2(η3-C3H5)4-SiO2 followed by treatment with H2 or O2, showed high activity in the selective oxidation of propene to acrylaldehyde.
Y. Iwasawa, N. Ito, H. Ishii and H. Kuroda, J. Chem. Soc., Chem. Commun., 1985, 827 DOI: 10.1039/C39850000827
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