(±)-Desepoxy-4,5-didehydromethylenomycin A and (±)-xanthocidin were synthesised via a common β-silyl enone intermediate obtained from an efficient, highly regioselective oxidation of an allylsilane.
B. Au-Yeung and Y. Wang, J. Chem. Soc., Chem. Commun., 1985, 825 DOI: 10.1039/C39850000825
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