Issue 9, 1985

The role of bivalent tin compounds in platinum co-ordination chemistry; X-ray structure of [Pt{Sn(NR′2)2}3], trans-[(Pt(µ-Cl)(PEt3){SnCl(NR′2)2})2], and (SnClR2)2[R = CH(SiMe3)2, R′= SiMe3]

Abstract

Bivalent tin compounds SnX2 behave in one of three ways towards platinum substrates: (a) as neutral ligands, (b) as co-ordinatively unsaturated fragments by inserting into Pt–Cl bonds, and (c) as reducing agents; these features are illustrated, inter alia, by X-ray data on the three title compounds.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1985, 548-550

The role of bivalent tin compounds in platinum co-ordination chemistry; X-ray structure of [Pt{Sn(NR′2)2}3], trans-[(Pt(µ-Cl)(PEt3){SnCl(NR′2)2})2], and (SnClR2)2[R = CH(SiMe3)2, R′= SiMe3]

T. A. K. Al-Allaf, C. Eaborn, P. B. Hitchcock, M. F. Lappert and A. Pidcock, J. Chem. Soc., Chem. Commun., 1985, 548 DOI: 10.1039/C39850000548

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