Issue 9, 1985
From the journal:

Journal of the Chemical Society, Chemical Communications

Characterization of a high-valent ruthenyl (RuIV[double bond, length half m-dash]O) cation stabilized by the macrocyclic 1,4,8,11-tetramethyl-1,4,8,11-tetra-azacyclotetradecane (tmc) ligand: crystal and molecular structure of trans-[RuIV(tmc)O(MeCN)][PF6]2

Chi-Ming Che,   Kwok-Yin Wong  and  Thomas C. W. Mak  

Abstract

trans-[RuIV(tmc)O(MeCN)][PF6]2(tmc = 1,4,8,11-tetramethyl-1,4,8,11-tetra-azacyclotetradecane) has been obtained by the reaction of PPh3 with trans-[RuVI(tmc)O2][PF6]2 in MeCN; the Ru[double bond, length half m-dash]O distance in this mono-oxo ruthenium(IV)(ruthenyl) species, as determined by X-ray crystallography, is 1.765(5)Å.

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Article information

DOI
https://doi.org/10.1039/C39850000546
Article type
Paper

J. Chem. Soc., Chem. Commun., 1985, 546-548

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Characterization of a high-valent ruthenyl (RuIV[double bond, length half m-dash]O) cation stabilized by the macrocyclic 1,4,8,11-tetramethyl-1,4,8,11-tetra-azacyclotetradecane (tmc) ligand: crystal and molecular structure of trans-[RuIV(tmc)O(MeCN)][PF6]2

C. Che, K. Wong and T. C. W. Mak, J. Chem. Soc., Chem. Commun., 1985, 546 DOI: 10.1039/C39850000546

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