1-Thiocyanatobuta-1,3-dienes react with strong dienophiles to produce directly the rearranged products of type (6)via a combination of a Diels–Alder reaction with a [3,3] sigmatropic shift.
S. Huber, P. Stamouli and R. Neier, J. Chem. Soc., Chem. Commun., 1985, 533 DOI: 10.1039/C39850000533
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