The reaction between tris(trimethylsilyl)methyl-lithium and manganese(II) or cobalt(II) chloride yields lithium salts with chloride-bridged polynuclear anions; the manganese compound [Li(thf)4][{(Me3Si)3C}3Mn3Cl4(thf)](thf = tetrahydrofuran) has been characterised by an X-ray study.
C. Eaborn, P. B. Hitchcock, J. D. Smith and A. C. Sullivan, J. Chem. Soc., Chem. Commun., 1985, 534 DOI: 10.1039/C39850000534
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