By reaction of [Ru(CO)3(PPh3)2] with 2-nitrophenol, the deep brown ruthenium(II) complex, [[graphic omitted]O-o)(OC6H4NO2-o)(CO)(PPh3)2], has been obtained. X-Ray crystallography has shown that the complex contains a o-nitrosophenolate ligand, which co-ordinates to ruthenium in a chelating fashion through its nitroso-nitrogen and phenolic oxygen atoms.
M. Pizzotti, C. Crotti and F. Demartin, J. Chem. Soc., Dalton Trans., 1984, 735 DOI: 10.1039/DT9840000735
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