A novel base-induced Polonovski-type reaction is described; the regiochemistry of the Polonovski and related reactions can be examined by using 2-methoxytetrahydro-6,12-methanodibenz[c.f]azocine N-oxide (1b) as a probe.
T. Nomoto and H. Takayama, J. Chem. Soc., Chem. Commun., 1984, 1644 DOI: 10.1039/C39840001644
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